S1E41 — Bungee × Punch × One Round Battle
Hunter x Hunter — Season 1, Episode 41.

Gon and Killua learn their types of Hatsu; Gon is an Enhancer and Killua is a Transmuter. Gon fights Hisoka, and while over-matched, gets a punch in and gives back the number badge that Hisoka gave him during the exam. After that, Hisoka fights with his full power.
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